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It's not quite as effective as taking three deep breaths, holding the last one, and then filling your mouth with vodka or something -- there, your tongue absorbs the alcohol and circulation delivers it right to the brain.
Even there, there's danger: if you're good at holding your breath, you can absorb enough alcohol to do serious harm.
Even there, there's danger: if you're good at holding your breath, you can absorb enough alcohol to do serious harm.

